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Title
DEDICATION
CERTIFICATE
DECLARATION
ACKNOWLEDGEMENT
CONTENTS
Preface
List of papers published in Journals
1 Periodic Precipitation Patterns: A General Introduction
1.1 Patterns in nature
1.2 Periodic precipitation in reaction-diffusion systems
1.3 The homogeneous A+B-->P type reaction-diffusion processes
1.4 The A+B-->P reaction-diffusion process with initially separated reactants
1.5 The Liesegang patterns
1.6 Characteristic laws of banding
1.6.1 Time law
1.6.2 Spacing law
1.6.3 Width law
1.7 Influences of electrolyte concentrations on banding: Matalon-Packter law
1.8 Role of gel matrix
1.9 Exotic morphological structures
1.10 Propagating patterns
1.11 Gravity effect on the formation of periodic precipitate patterns
1.12 Stabilization effect of electric field on stochastic precipitate pattern formation
1.13 Secondary Liesegang patterns
1.14 Periodic precipitation in multi-component systems
1.15 Conclusions
References
2 Theories of Liesegang Phenomena
2.1 Introduction
2.2 Morse and Pierce model
2.3 The Wagner model
2.4 The Prager model
2.5 The Kelley and Rubinow model
2.6 Dew, LeVan & Ross models
2.7 Dhar, Shinohara models
2.8 The Spinodal decomposition scenario
2.9 Conclusions
References
3 The Moving Boundary Model: A New Approach
3.1 Introduction
3.2 The moving boundary model
3.3 The new model and the width law
3.4 Conclusions
References
4 The Matalon-Packter Law: A Fresh Perspective
4.1 Introduction
4.2 Derivation of Matalon-Packter law
4.3 Numerical study on Matalon-Packter law
4.4 Conclusions
References
5 Experimental Verification of the New Model in Different Systems
5.1 Introduction
5.2 Precipitate bands in agar-agar gel
5.2.1 PbF2 patterns
5.2.2 CuCr2O7 bands
5.2.3 PbCO3 bands
5.3 Precipitate bands in silica gel
5.3.1 CuCr2O7 bands
5.3.2 Ca (PO4) 2 bands
5.3.3 SrF2 bands
5.3.4 bamboo bands
5.4 Verification of the laws of patterning
5.4.1 Modified time law
5.4.2 Modified spacing law and determination of new spacing coefficient
5.4.3 En-ΔEn plots and spacing coefficient
5.4.4 Modified width law
5.5 Conclusions
References
6 The Role of colloid dynamics
6.1 Introduction
6.2 Estimation of diffusion coefficient
6.3 multi-component systems
6.4 Role of fast colloidal dynamics
6.5 Conclusions
References
7 Migrating triplet bands in gelatinous matrix
7.1 Introduction
7.2 Experimental
7.3 The three phases of calcium phosphates
7.4 Propagation of patterns
7.5 Estimation of the spacing coefficient
7.6 Conclusions
References
8 Summary and scope for further studies
8.1 Summary
8.2 Scope for further studies
References