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  • Title
  • DEDICATION
  • CERTIFICATE
  • DECLARATION
  • ACKNOWLEDGEMENT
  • CONTENTS
  • Preface
  • 1 Introduction
  • 1.1 General introduction
  • 1.2 Brief review
  • 1.2.1 Pure liquids
  • 1.2.2 Binary mixtures
  • 1.2.3 Ternary mixtures
  • 1.2.4 Acoustic nonlinearity parameter (B/A)
  • 1.3 Present study
  • 1.4 References
  • 2 Theoretical Details and Experimental Methods
  • 2.1 Theoretical details
  • 2.1.1 Flory Patterson theory
  • 2.1.2 Free length theory
  • 2.1.3 Collision factor theory
  • 2.1.4 Nomotos relation
  • 2.1.5 Van Dael and Van Geels ideal mixture relation
  • 2.1.6 Acoustic nonlinearity parameter (B/A)
  • 2.2 Experimental methods
  • 2.2.1 introduction
  • 2.2.2 Pulse technique
  • 2.2.3 Pulse echo overlap method
  • 2.2.4 MATEC ultrasonic velocity measuring system
  • 2.2.5 Liquid cell
  • 2.2.6 Density measurements
  • 2.2.7 Viscosity measurements
  • 2.3 References
  • 3 Computational Procedure and Computer Program
  • 3.1 Computational procedure
  • 3.1.1 Introduction
  • 3.1.2Mole fraction and molar volume
  • 3.1.3 Compressibility
  • 3.1.4 Free volume
  • 3.1.5 Internal pressure
  • 3.1.6 Intermolecular free length
  • 3.1.7 Available volume
  • 3.1.8 Specific acoustic impedance
  • 3.1.9 Enthalpy
  • 3.1.10 Raos constant
  • 3.1.11 Wadas constant
  • 3.1.12 Van der Waals constant
  • 3.1.13 Degree of molecular interaction
  • 3.1.14 Surface tension
  • 3.1.15 Excess functions
  • 3.1.16 Percentage deviation in velocity
  • 3.2 Description of computer program
  • 3.3 References
  • 4 Ultrasonic Study of Binary Mixtures of Toluene with n-Alkanols
  • 4.1 Introduction
  • 4.2 Experimental data
  • 4.3 Results and discussion
  • 4.4 Conclusion
  • 4.5 References
  • 5 Ultrasonic Study of Ternary Mixtures of Methyl Ethyl Ketone and n-Nonane with n-Alkanols
  • 5.1 Introduction
  • 5.2 Experimental data
  • 5.3 Results and discussion
  • 5.4 Conclusion
  • 5.5 References
  • 6 Ultrasonic Study of Binary Mixtures of Acetonitrile / Benzonitrile in Methanol / Toluene
  • 6.1 Introduction
  • 6.2 Experimental
  • 6.3 Results and discussion
  • 6.3.1 Ultrasonic velocity
  • 6.3.2 Thermo-acoustical parameters
  • 6.3.3 Excess thermodynamic functions
  • 6.3.4 Thermodynamic parameters and nonlinearity parameter (B/A)
  • 6.4 Conclusion
  • 6.5 References
  • 7 Ultrasonic Study of Binary Mixtures of Methyl Ethyl Ketone / Methyl Phenyl Ketone in Methanol Toluene
  • 7.1 Introduction
  • 7.2 Experimental
  • 7.3 Results and discussion
  • 7.3.1 Ultrasonic velocity
  • 7.3.2 Thermo-acoustical parameters
  • 7.3.3 Excess thermodynamic functions
  • 7.3.4 Thermodynamic parameters and nonlinearity parameter (B/A)
  • 7.4 Conclusion
  • 7.5 References
  • 8 Ultrasonic Study of Ternary Mixtures of Methyl Ethyl Ketone and Toluene with n-Alkanols
  • 8.1 Introduction
  • 8.2 Experimental
  • 8.3 Results and discussion
  • 8.3.1 Ultrasonic velocity
  • 8.3.2 Thermo-acoustical parameters
  • 8.3.3 Excess thermodynamic functions
  • 8.3.4 Thermodynamic parameters and nonlinearity parameter (B/A)
  • 8.4 Conclusion
  • 8.5 References
  • 9 Ultrasonic Study of Ternary Mixtures of Methyl Phenyl Ketone and Toluene with n-Alkanols
  • 9.1 Introduction
  • 9.2 Experimental
  • 9.3 Results and discussion
  • 9.3.1 Theoretical velocity
  • 9.3.2 Thermo-acoustical parameters
  • 9.3.3 Excess thermodynamic functions
  • 9.3.4 Thermodynamic parameters and nonlinearity parameter (B/A)
  • 9.4 Conclusion
  • 9.5 References