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  • TITLE
  • DEDICATION
  • CERTIFICATE
  • DECLARATION
  • ACKNOWLEDGEMENT
  • CONTENTS
  • GLOSSARY OF TERMS
  • PREFACE
  • I INTRODUCTION
  • I.1 Types of Carbon Blacks
  • I.2 Types of Non-black Fillers
  • I.3 Reinforcement of Elastomers by Fillers
  • I.4 Effect of Filler on Viscosity of the Rubber Compound
  • I.5 Effect of Filler on Crosslinking Process andCure Characteristics
  • I.6 Effect of Filler on Vulcanisate Properties
  • I.7 Specific Properties Imparted by Fillers
  • I.8 Effect of Filler on Thermal Conductivity ofRubber Compounds
  • I.9 Heat Transfer and Vulcanisation of Thick Articles
  • I.10 Scope of the Work
  • I.11 Objectives of the Work
  • References
  • II EXPERIMENTAL TECHNIQUES
  • II.1 Materials Used
  • II.2 Preparation of Compounds
  • II.3 Testing of Compounds
  • II.4 Moulding of Test Samples
  • II.5 Testing for Vulcanisate Properties
  • II.6 Volume Fraction of Rubber in Swollen Vulcanisate (Vr)
  • II.7 Measurement of Resistance to Degradation
  • Fig. II.3 Gamma Chamber 900
  • II.8 Measurement of Rheological Properties
  • II.9 Measurement of Thermal Conductivity
  • Fig. II.5 Quick Thermal Conductivity Meter QTM-D3
  • Fig. II.6 Quick Thermal Conductivity Meter
  • II.10 Measurement of Electrical Properties
  • References
  • III EFFECT OF ALUMINIUM POWDER ON CURE CHARACTERISTICS AND VULCANISATION KINETICS OF NATURAL RUBBER COMPOUNDS
  • III.1 Effect of Fillers on Scorch Time
  • III.2 Effect of Fillers on Cure Time and Cure R a t e Index
  • III.3 Effect of Fillers on Activation Energy
  • III.4 Effect of Filler on Rate Constant K
  • III.5 Conclusions
  • References
  • IV STUDIES ON RHEOLOGICAL BEHAVIOUR OF NATURAL RUBBER COMPOUNDS CONTAINING ALUMINIUM POWDER
  • IV.1 Effect of Shear Stress on Viscosity
  • IV.2 Effect of Shear Rate on Viscosity
  • IV.3 Effect of Temperature and Shear Rate on Viscosity
  • IV.4 Effect of Temperature and Quantity of Filler on Flow Behaviour Index (n)
  • IV.5 Effect of Aluminium Powder on Die Swell
  • IV.6 Deformation of Extrudates
  • Fig. IV.6 Photograph of the extrudates at three shearrates at 100oC
  • IV.7 Conclusions
  • References
  • V TECHNOLOGICAL PROPERTIES OF ALUMINIUM POWDER- FILLED VULCANISATES
  • V.1 Tensile Strength, Modulus and Elongation at Break
  • V.2 Tear Strength
  • V.3 Hardness
  • V.4 Rebound Resilience
  • V.5 Compression Set
  • V.6 Din Abrasion Loss
  • V.7 Conclusions
  • References
  • VI THERMAL CONDUCTIVITY OF ALUMINIUM POWDER-FILLED NATURAL RUBBER VULCANISATES
  • VI. 1 Effect of Fillers on Thermal Conductivity
  • VI.2 Effect of Temperature on Thermal Conductivity
  • VI.3 Effect of Thermal Conductivity on Extent of Cross linking
  • VI.4 Effect of Aluminum Powder on Electrical Resistivity
  • VI.5 Conclusions
  • References
  • VII AGEING CHARACTERISTICS OF ALUMINIUM POWDER-FILLED NATURAL RUBBER VULCANISATES
  • VII.1 Effect of Heat Ageing on Tensile Strength
  • VII.2 Effect of γ-Radiation on Tensile Strength
  • VII.3 Ozone Resistance of the Vulcanisates
  • Fig. VII.l Optical photographs of ozone exposed samples (2 hours)
  • Fig. VII.2 Optical photographs of ozone exposed samples (20 hours)
  • VII.4 Conclusions
  • References
  • VIII EVALUATION OF ALUMINIUM POWDER IN TRUCK TYRE RETREAD COMPOUND
  • VIII.1 Properties of TR., TRAL, TRAL10, TRAL15 and TRAL 20 Compounds
  • VIII.2 Properties of Vulcanisates Containing Aluminium Powder in Polybutadiene Phase
  • VIII.3 Properties of Compound Containing Aluminium Powder Dispersed in NR Phase
  • VIII.4 Conclusions
  • References
  • SUMMARY AND CONCLUSIONS
  • Scope for Further Work
  • LIST OF PUBLICATIONS CONNECTED WITH THIS WORK