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Title
DEDICATION
CERTIFICATE
DECLARATION
ACKNOWLEDGEMENT
CONTENTS
Preface
1 Introduction
1.1 General introduction
1.2 Brief review
1.2.1 Pure liquids
1.2.2 Binary mixtures
1.2.3 Ternary mixtures
1.2.4 Acoustic nonlinearity parameter (B/A)
1.3 Present study
1.4 References
2 Theoretical Details and Experimental Methods
2.1 Theoretical details
2.1.1 Flory Patterson theory
2.1.2 Free length theory
2.1.3 Collision factor theory
2.1.4 Nomotos relation
2.1.5 Van Dael and Van Geels ideal mixture relation
2.1.6 Acoustic nonlinearity parameter (B/A)
2.2 Experimental methods
2.2.1 introduction
2.2.2 Pulse technique
2.2.3 Pulse echo overlap method
2.2.4 MATEC ultrasonic velocity measuring system
2.2.5 Liquid cell
2.2.6 Density measurements
2.2.7 Viscosity measurements
2.3 References
3 Computational Procedure and Computer Program
3.1 Computational procedure
3.1.1 Introduction
3.1.2Mole fraction and molar volume
3.1.3 Compressibility
3.1.4 Free volume
3.1.5 Internal pressure
3.1.6 Intermolecular free length
3.1.7 Available volume
3.1.8 Specific acoustic impedance
3.1.9 Enthalpy
3.1.10 Raos constant
3.1.11 Wadas constant
3.1.12 Van der Waals constant
3.1.13 Degree of molecular interaction
3.1.14 Surface tension
3.1.15 Excess functions
3.1.16 Percentage deviation in velocity
3.2 Description of computer program
3.3 References
4 Ultrasonic Study of Binary Mixtures of Toluene with n-Alkanols
4.1 Introduction
4.2 Experimental data
4.3 Results and discussion
4.4 Conclusion
4.5 References
5 Ultrasonic Study of Ternary Mixtures of Methyl Ethyl Ketone and n-Nonane with n-Alkanols
5.1 Introduction
5.2 Experimental data
5.3 Results and discussion
5.4 Conclusion
5.5 References
6 Ultrasonic Study of Binary Mixtures of Acetonitrile / Benzonitrile in Methanol / Toluene
6.1 Introduction
6.2 Experimental
6.3 Results and discussion
6.3.1 Ultrasonic velocity
6.3.2 Thermo-acoustical parameters
6.3.3 Excess thermodynamic functions
6.3.4 Thermodynamic parameters and nonlinearity parameter (B/A)
6.4 Conclusion
6.5 References
7 Ultrasonic Study of Binary Mixtures of Methyl Ethyl Ketone / Methyl Phenyl Ketone in Methanol Toluene
7.1 Introduction
7.2 Experimental
7.3 Results and discussion
7.3.1 Ultrasonic velocity
7.3.2 Thermo-acoustical parameters
7.3.3 Excess thermodynamic functions
7.3.4 Thermodynamic parameters and nonlinearity parameter (B/A)
7.4 Conclusion
7.5 References
8 Ultrasonic Study of Ternary Mixtures of Methyl Ethyl Ketone and Toluene with n-Alkanols
8.1 Introduction
8.2 Experimental
8.3 Results and discussion
8.3.1 Ultrasonic velocity
8.3.2 Thermo-acoustical parameters
8.3.3 Excess thermodynamic functions
8.3.4 Thermodynamic parameters and nonlinearity parameter (B/A)
8.4 Conclusion
8.5 References
9 Ultrasonic Study of Ternary Mixtures of Methyl Phenyl Ketone and Toluene with n-Alkanols
9.1 Introduction
9.2 Experimental
9.3 Results and discussion
9.3.1 Theoretical velocity
9.3.2 Thermo-acoustical parameters
9.3.3 Excess thermodynamic functions
9.3.4 Thermodynamic parameters and nonlinearity parameter (B/A)
9.4 Conclusion
9.5 References