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  • Title
  • DEDICATION
  • CERTIFICATE
  • DECLARATION
  • ACKNOWLEDGEMENT
  • CONTENTS
  • Preface
  • 1 General Introduction
  • 1.1 The Glassy State
  • 1.2 Definition of a Glass
  • 1.3 Formation of Glass
  • 1.3.1 Glasses Front Melts
  • 1.3.2 Sol-Gel Processing
  • 1.4 Structure and Topology
  • 1.5 Glass as Laser Host
  • 1.6 Spectroscopy of Rare Earths in Glass
  • 1.6.1 Judd-Ofelt Theory
  • 1.6.2 Energy Transfer in Doped Glasses
  • 1.6.3 Phonon Sideband (PSB) Spectroscopy
  • 1.7 Sol-Gel Thin Films and Applications
  • 1.7.1 Luminescent Antireflection Coatings (LARC)
  • 1.7.2 Fiber Optic pH Sensors
  • References
  • 2 Spectral and Laser Analysis of Mn2+: Pr3+System in Phosphate Glasses
  • 2.1 Introduction
  • 2.2 Experimental
  • 2.3 Spectroscopic Parameters
  • 2.4 Radiative Transition Parameters
  • 2.5 Nonradiative Decay Processes
  • 2.6 Results and Discussion
  • 2.7 Conclusions
  • References
  • 3 Modified Judd-Ofelt Analysis of Pr3+ in Silica and Phosphate Glasses
  • 3.1 Introduction
  • 3.2 Theoretical Model I
  • 3.3 Theoretical Model II
  • 3.4 Experimental
  • 3.5 Results And Discussion
  • 3.6 Conclusions
  • References
  • 4 Phonon Sideboards and Local Vibrational Analysis of Eu3+ Doped Glasses
  • 4.1 Introduction
  • 4.2 Experimental Procedure
  • 4.3 Theoretical Background
  • 4.4 Results and Discussion
  • 4.5 Conclusions
  • References
  • 5 Synthesis Characterisation and Applications of Sol-Gel Thin Films
  • 5.1 Introduction
  • 5.2 Theory of Sol-Gel Dip Coating
  • 5.3 PC Based Dip Coating System
  • 5.3.1 Hardware Description of the System
  • 5.3.2 Mechanical Part of the System
  • 5.3.3 Software for the System
  • 5.4 Luminescent Antireflection Coating (LARC) as Solar Collectors
  • 5.4.1 Efficiency of Solar Cells
  • 5.4.2 Film Formation
  • 5.4.3 Optical Response of the Films
  • 5.4.4 Photovoltaic Characteristics
  • 5.5 Evanescent Wave Based Fiber Optic pH Sensor (Optode)
  • 5.5.1 Experimental Procedure
  • 5.5.2 Results and Discussion
  • 5.6 Conclusions
  • References
  • APPENDIX A