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  • TITLE
  • DEDICATION
  • CERTIFICATE
  • DECLARATION
  • ACKNOWLEDGEMENT
  • ABBREVIATIONS
  • CONTENTS
  • 1. INTRODUCTION AND OBJECTIVES
  • 2. PHOTORESPONSIVE AZO POLYMERS: CONCEPTS, CHARACTERISTICS AND APPLICATIONS
  • 1. Spectral Response
  • 2. Viscosity
  • 3. pH and conductivity
  • 4. Solubility
  • 5. Surface Free Energy
  • 6. Photomechanical Effects
  • 7. Membrane Permeability
  • 8. Photoresponsive Metal Ion Chelation
  • 9. Helix Reversal of Photochromic Polypeptides
  • 10. Photochromism in Polymer Matrix
  • 11. Applications
  • 3. SYNTHESIS AND THERMAL STUDIES OF PHOTORESPONSIVE AZO POLYMERS
  • 1. Synthesis of Polyesters with Azobenzene Residues in the Side Chain
  • 2. Synthesis of Polyesters with Azobenzene Crosslinks
  • 3. Synthesis of Polyesters with Azobenzene Residues in the Backbone
  • 4. Thermal Stability of Polyesters with Azo Groups in the Polymer Backbone
  • 4.1 Phenomenological Aspects
  • 4.2 Evaluation of Kinetic Parameters
  • 4. PHOTOSTIMULATED PROPERTY CHANGES OF AZO POLYMERS
  • 1. Photo-induced Viscosity Changes of Polyvinyl Esters with Pendant Azobenzene Groups
  • 2. Photo-induced Viscosity Changes of Polyvinyl Esters with Pendant Azobenzene Groups in Presence of Protic or Lewis Acids
  • 3. Photo-induced Viscosity Changes of Polyesters with Azobenzene Groups in the Backbone
  • 4. Photo-effect on Conductivity of Polymers
  • 4.1 Photo-induced Conductivity Changes of Polyvinyl Esters (AZO PVE) with Pendant Azobenzene groups
  • 4.2. Photo-induced Conductivity Changes of Polyesters (PE) with Azo Linkages in the Backbone
  • 5. Photostimulated Dilation Changes in Polyvinyl Esters with Azobenzene Crosslinks
  • 5. EXPERIMENTAL
  • 5.1. General
  • 5.2. Photo-induced Property Changes of AZO PVE 1a (20)
  • 5.3. Photo-induced Property Chenges of AZO PVE 1b (21)
  • 5.4. Photo-induced Property Changes of AZO PVE 1c (22)
  • 5.5. Photo-induced Property Changes of AZO PVE 2a (23)
  • 5.6. Photo-induced Property Changes of AZO PVE 2b (24)
  • 5.7. Photo-induced Property Changes of AZO PVE 2c (25)
  • 5.8. Photo-induced Property Changes of PE 1a (31)
  • 5.9. Photo-induced Property Changes of PE 1b (32)
  • 5.10. Photo-induced Property Changes of PE 1c (33)
  • 5.11. Photeinduced Property Changes of PE 2a (34)
  • 5.12. Photo-induced property changes of PE 2b (35)
  • 5.13. Photo-induced Property Changes of PE 2c
  • 5.14. Photo-induced Property Changes of PE 3a (37)
  • 5.15. Photo-induced Property Changes of PE 3b (38)
  • 5.16. Photo-induced Property Changes of Polymer PE 3c (39)
  • 5.17. Photo-induced Property Changes of PE 4c (40)
  • 5.18. Photo-induced Property Changes of PE 4b (41)
  • 5.19. Photo-induced Property Changes of PE 4c (42)
  • 5.20. Photo-induced Property Changes of PE 5a (43)
  • 5.21. Photo-induced Property Changes of PE 5b (44)
  • 5.22. Photo-induced Property Changes of PE 5c (45)
  • 5.23. Thermogravimetry
  • 6. SUMMARY AND OUTLOOK
  • REFERENCES