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  • Title
  • CERTIFICATE
  • DECLARATION
  • ACKNOWLEDGEMENT
  • List of Notations and Abbreviations
  • List of Tables
  • List of Figures
  • CONTENTS
  • Preface
  • 1. Introduction
  • 1.1. Iron - General chemistry
  • 1.2. Cobalt - General chemistry
  • 1.3. Nickel - General chemistry
  • 1.4. Copper - General chemistry
  • 1.5. Applications of transition metal complexes
  • 1.6. First row transition metal complexes of antipyrine and its derivatives: a review
  • 2. Reagents and Physicochemical Methods
  • 2.1. Reagents
  • 2.2. Analyses of Complexes
  • 2.3. Physicochemical methods used in the present study
  • 3. Studies on iron (lll), Cobalt (ll), Nickel (Il) and Copper (Il) Complexes of 1, 2- (Diimino-4 -antipyrnyl) ethane
  • 3.1. Procedures for the preparation of the complexes
  • 3.2. Results and discussion
  • 3.3. Summary and conclusion
  • 4. Studies on iron (lll), Cobalt (ll), Nickel (Il) and Copper (Il) Complexes of 4-N- (4 - Antipyrylmethylidene) aminoantipyrine
  • 4.1. Preparation of the complexes
  • 4.2. Results and discussion
  • 5. Thermal Studies on Transition Metal Complexes of Some Antipyrne Derivatives
  • 5.1. Experimental
  • 5.2. Results and discussion
  • 5.3. Phenomenological aspects
  • 5.4. Kinetic aspects
  • 5.5. Mechanistic aspects
  • 5.6. Summary and conclusion
  • 6. Summary and Conclusion
  • 6.1 Complexes of GA
  • 6.2. Complexes of AA
  • 6.3. Thermal studies on complexes of GA and AA
  • Tables and Figures
  • References