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  • TITLE
  • DEDICATION
  • CERTIFICATE
  • DECLARATION
  • ACKNOWLEDGEMENT
  • NOTATIONS AND ABBREVIATIONS
  • CONTENTS
  • 1. INTRODUCTION
  • 1.1 Monocarboxylates: Structure and Bonding
  • 1.2 Dicarboxylates: Structure and Bonding
  • 1.3 Carboxyl group in Biology
  • 1.4 Metal Carboxylates as Synthetic Model Complexes
  • 1.5 Metal carboxylates in Catalysis
  • 1.6. Scope and Objectives
  • Reference
  • 2. REAGENTS AND PHYSICO-CHEMICAL METHODS
  • 2.1 Reagents
  • 2.2 Preparative Details
  • 2.3 Elemental Analysis
  • 2.4 Spectral Methods
  • 2.5 Coordination Chemistry of Copper (II)
  • 2.6 Coordination Chemistry of Cobalt (II)
  • 2.7 Coordination Chemistry of Nickel (II)
  • 2.8 Thermal Analysis
  • 2.9 Magnetic Susceptibility Measurements
  • References
  • 3. INTERACTION OF LEWIS-BASESWITH POLYMERIC METAL (II) SUCCINATES
  • 3.1 Introduction
  • 3.2 Experimental
  • 3.3 Results and Discussion
  • 3.3.1 Metal succinates of Ni (II), Co (II) and Cu (II)
  • 3.3.2 Lewis-base mediated fragmentation of nickel (II) succinate
  • 3.3.3 IR spectra of Lewis-base adducts of nickel (II) succinate
  • 3.3.4 Electronic spectra and magnetic data of Lewis-base adducts of nickel (II) succinate
  • 3.3.5 Lewis-base mediated fragmentation of polymeric cobalt (II) succinate
  • 3.3.6 IR spectra of Lewis-base adducts of cobalt (II) succinate
  • 3.3.7 Electronic spectra and magnetic data of Lewis-base adducts of cobalt (II) succinate
  • 3.3.8 Lewis-base mediated fragmentation of polymeric copper (II) succinate
  • 3.3.9 IR spectra of Lewis-base adducts of copper (II) succinate
  • 3.3.10 Electronic spectra and magnetic data of Lewis-base adducts of copper (II) succinate
  • 3.3.11 EPR Spectra of Lewis-base adducts of copper (II) succinate
  • 3.3.12 Crystal and Molecular structure
  • References
  • 4. THERMAL DISSOCIATION FEATURES OFSUCCINATE COMPLEXES OF NI (II), CO (II) AND CU (II) AND THEIR LEWIS-BASE ADDUCTS
  • 4.1 Introduction
  • 4.2 Results and Discussion
  • 4.2.1 Phenomenological Aspects
  • 4.2.2 Kinetic Aspects
  • 4.2.3 Mechanistic Aspects
  • 4.2.4 Trend in Thermal Behaviour of metal succinates and their Adducts
  • References
  • 5. INTERACTION OF LEWIS-BASESWITH POLYMERIC METAL (II) MALONATES
  • 5.1 Introduction
  • 5.2 Experimental
  • 5.3. Results and Discussion
  • 5.3.1. Metal malonates of Ni (II), Co (II) and Cu (II)
  • 5.3.2 Lewis-base mediated fragmentation of polymericnickel (II) malonate
  • 5.3.3 IR spectra of Lewis-base adducts of nickel (II) malonate
  • 5.3.4 Electronic spectra and magnetic data of Lewis-base adductsof nickel (II) malonate
  • 5.3.5 Lewis-base mediated fragmentation of polymeric cobalt (II) malonate
  • 5.3.6 IR spectra of Lewis-base adducts of cobalt (II) malonate
  • 5.3.7 Electronic spectra and magnetic data of Lewis-baseadducts of cobalt (II) malonate
  • 5.3.8 Interaction of Lewis-bases with polymeric copper (II) malonate
  • 5.3.9 IR spectra of Lewis-base adducts of copper (II) malonate
  • 5.3.10 Electronic spectra and magnetic data of Lewis-baseadducts of copper (II) malonate
  • 5.3.11. Crystal and Molecular structure
  • 5.3.12 EPR spectra of Lewis-base adducts of copper (II) malonate.
  • References
  • 6 THERMAL DISSOCIAN FEATURES OF MALONATE COMPLEXES OF Ni (II), Co (ii) and Cu AND THEIR LEWS-BASE ADDUCTS
  • 6.1 Introduction
  • 6.2 Result Disscusion
  • 6.2.1.2 Lewis- base adductsof nickel (II) malonate
  • 6.2.1.3 Thermal decomposition cobalt (II) malonate in N2
  • 6.2.4 Trends in thermal behaviour of metal malonates and their adducts.
  • References
  • 7 INTERACTION OF LEWIS-BASES WITH POLYMERIC METAL (II) OXALATES
  • 7.1 INTRODUCTION
  • 7.2 Experimental
  • 7.3 Results and Discussion
  • 7.3.1 Metal Oxalate of Ni (II, Co (ii) and Cu (II)
  • 7.3, 2 Interaction of Lewis-bases with polymeric nickel (II) oxalate
  • 7.3.4 Electronic spectra and magnetic data of Lewis base adducts of nickel (II) oxalate
  • 7.3.7 Electronic spectra and magnetic data of Lewis base adducts of Cobalt (II) oxalate
  • References
  • 8 THERMAL DISSOCIATION FEATURES OF OXALATE COMPLEXES OF Ni (II), Co (II) AND Cu (II) AND THEIR LEWIS- BASE ADDUCTS
  • 8.1 Introduction
  • 8.2 Results and Discussion
  • References
  • 9 INTERACTION OF LEWIS-BASES WITH POLYMERIC METAL (II) TEREPHTHALATES
  • 9.1 Introduction
  • 9.2 Experimental
  • 9.3 Results and Discussion
  • References
  • 10 SUMMARY AND CONCLUSION