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  • TITLE
  • DEDICATION
  • STATEMENT
  • CERTIFICATE
  • ACKNOWLEDGEMENT
  • CONTENTS
  • PREFACE
  • ABBREVIATIONS
  • 1 AN INTRODUCTION TO THE CYCLOADDITION CHEMISTRY OF o-QUINONES AND o-THIOQUINONES
  • 1.1 General
  • 1.2 General Introduction to o-Quinones
  • 1.2.1 Cycloaddition Reactions of o-Quinones
  • 1.2.1.a o-Quinone as Carbodiene
  • 1.2. I.b o-Quinone as Heterodiene
  • 1.2.1.c o-Quinone as Dienophile
  • 1.2.1.d o-Quinone as Heterodienophile
  • 1.2.1.e o-Quinone as Dipolarophile
  • 1.3 General Introduction to o-Thioquinones
  • 1.3.1 Synthesis of o-Thioquinones
  • 1.3.2 Cycloaddition Reactions of o-Thioquinones
  • 1.3.2.a o-Thioquinone as Heterodiene
  • 1.3.2.b o-Thioquinone as Heterodienophile
  • 1.4 Importance of 1, 4-Dioxins and 1, 4-Oxathiins
  • 1.5 Theoretical Calculations
  • 1.6 Definition of the Problem
  • 1.7 References
  • 2 CYCLOADDITION REACTIONS OF o-THIOQUINONES WITH ACYCLIC, CARBOCYCLIC AND HETEROCYCLIC DIENES
  • 2.1 Introduction
  • 2.2 The Present Work
  • 2.3 Results and Discussion
  • 2.3.1 Cycloadditions with Acyclic Dienes
  • 2.3.2 Cycloadditions with Carbocyclic Dienes
  • 2.3.3 Cycloadditions with Heterocyclic Dienes
  • 2.4 Theoretical Calculations
  • 2.5 Experimental
  • 2.6 References
  • 3 CYCLOADDITION REACTIONS OF o-THIOQUINONES WITH FULVENES
  • 3.1 Introduction
  • 3.2 The Present Work
  • 3.3 Results and Discussion
  • 3.4 Theoretical Calculations
  • 3.5 Experimental
  • 3.6 References
  • 4 CYCLOADDITION REACTIONS OF o-THIOQUINONES WITH ALKENES AND ALKYNES
  • 4.1 Introduction
  • 4.2 The Present Work
  • 4.3 Results and Discussion
  • 4.3.1 Cycloadditions with Alkenes
  • 4.3.2 Cycloadditions with Alkynes
  • 4.4 Experimental
  • 4.5 References
  • SUMMARY
  • LIST OF PUBLICATIONS