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TITLE
DEDICATION
CERTIFICATE
DECLARATION
ACKNOWLEDGEMENT
NOTATIONS AND ABBREVIATIONS
CONTENTS
1. INTRODUCTION
1.1 Monocarboxylates: Structure and Bonding
1.2 Dicarboxylates: Structure and Bonding
1.3 Carboxyl group in Biology
1.4 Metal Carboxylates as Synthetic Model Complexes
1.5 Metal carboxylates in Catalysis
1.6. Scope and Objectives
Reference
2. REAGENTS AND PHYSICO-CHEMICAL METHODS
2.1 Reagents
2.2 Preparative Details
2.3 Elemental Analysis
2.4 Spectral Methods
2.5 Coordination Chemistry of Copper (II)
2.6 Coordination Chemistry of Cobalt (II)
2.7 Coordination Chemistry of Nickel (II)
2.8 Thermal Analysis
2.9 Magnetic Susceptibility Measurements
References
3. INTERACTION OF LEWIS-BASESWITH POLYMERIC METAL (II) SUCCINATES
3.1 Introduction
3.2 Experimental
3.3 Results and Discussion
3.3.1 Metal succinates of Ni (II), Co (II) and Cu (II)
3.3.2 Lewis-base mediated fragmentation of nickel (II) succinate
3.3.3 IR spectra of Lewis-base adducts of nickel (II) succinate
3.3.4 Electronic spectra and magnetic data of Lewis-base adducts of nickel (II) succinate
3.3.5 Lewis-base mediated fragmentation of polymeric cobalt (II) succinate
3.3.6 IR spectra of Lewis-base adducts of cobalt (II) succinate
3.3.7 Electronic spectra and magnetic data of Lewis-base adducts of cobalt (II) succinate
3.3.8 Lewis-base mediated fragmentation of polymeric copper (II) succinate
3.3.9 IR spectra of Lewis-base adducts of copper (II) succinate
3.3.10 Electronic spectra and magnetic data of Lewis-base adducts of copper (II) succinate
3.3.11 EPR Spectra of Lewis-base adducts of copper (II) succinate
3.3.12 Crystal and Molecular structure
References
4. THERMAL DISSOCIATION FEATURES OFSUCCINATE COMPLEXES OF NI (II), CO (II) AND CU (II) AND THEIR LEWIS-BASE ADDUCTS
4.1 Introduction
4.2 Results and Discussion
4.2.1 Phenomenological Aspects
4.2.2 Kinetic Aspects
4.2.3 Mechanistic Aspects
4.2.4 Trend in Thermal Behaviour of metal succinates and their Adducts
References
5. INTERACTION OF LEWIS-BASESWITH POLYMERIC METAL (II) MALONATES
5.1 Introduction
5.2 Experimental
5.3. Results and Discussion
5.3.1. Metal malonates of Ni (II), Co (II) and Cu (II)
5.3.2 Lewis-base mediated fragmentation of polymericnickel (II) malonate
5.3.3 IR spectra of Lewis-base adducts of nickel (II) malonate
5.3.4 Electronic spectra and magnetic data of Lewis-base adductsof nickel (II) malonate
5.3.5 Lewis-base mediated fragmentation of polymeric cobalt (II) malonate
5.3.6 IR spectra of Lewis-base adducts of cobalt (II) malonate
5.3.7 Electronic spectra and magnetic data of Lewis-baseadducts of cobalt (II) malonate
5.3.8 Interaction of Lewis-bases with polymeric copper (II) malonate
5.3.9 IR spectra of Lewis-base adducts of copper (II) malonate
5.3.10 Electronic spectra and magnetic data of Lewis-baseadducts of copper (II) malonate
5.3.11. Crystal and Molecular structure
5.3.12 EPR spectra of Lewis-base adducts of copper (II) malonate.
References
6 THERMAL DISSOCIAN FEATURES OF MALONATE COMPLEXES OF Ni (II), Co (ii) and Cu AND THEIR LEWS-BASE ADDUCTS
6.1 Introduction
6.2 Result Disscusion
6.2.1.2 Lewis- base adductsof nickel (II) malonate
6.2.1.3 Thermal decomposition cobalt (II) malonate in N2
6.2.4 Trends in thermal behaviour of metal malonates and their adducts.
References
7 INTERACTION OF LEWIS-BASES WITH POLYMERIC METAL (II) OXALATES
7.1 INTRODUCTION
7.2 Experimental
7.3 Results and Discussion
7.3.1 Metal Oxalate of Ni (II, Co (ii) and Cu (II)
7.3, 2 Interaction of Lewis-bases with polymeric nickel (II) oxalate
7.3.4 Electronic spectra and magnetic data of Lewis base adducts of nickel (II) oxalate
7.3.7 Electronic spectra and magnetic data of Lewis base adducts of Cobalt (II) oxalate
References
8 THERMAL DISSOCIATION FEATURES OF OXALATE COMPLEXES OF Ni (II), Co (II) AND Cu (II) AND THEIR LEWIS- BASE ADDUCTS
8.1 Introduction
8.2 Results and Discussion
References
9 INTERACTION OF LEWIS-BASES WITH POLYMERIC METAL (II) TEREPHTHALATES
9.1 Introduction
9.2 Experimental
9.3 Results and Discussion
References
10 SUMMARY AND CONCLUSION